The linked reference & following summary discusses the positive feedback caused by the acidification of the oceans reducing sulfur flux from the ocean which then results in more radiative forcing (see the attached image) particularly over the Southern Ocean; however, I wonder what all of the fresh water (cited by Hansen et al 2015) will do the plankton producing all of this dimethylsulphide. If the freshwater kills the associated plankton then this could also be a very strong positive feedback mechanism (that Hansen et al 2015 do not consider):
http://www.nature.com/nclimate/journal/vaop/ncurrent/full/nclimate1981.htmlGlobal warming amplified by reduced sulphur fluxes as a result of ocean acidification; Katharina D. Six, Silvia Kloster, Tatiana Ilyina, Stephen D. Archer, Kai Zhang & Ernst Maier-Reimer; Nature Climate Change; (2013); doi:10.1038/nclimate1981
http://www.mpimet.mpg.de/nc/en/communication/news/single-news/article/climate-change-ocean-acidification-amplifies-global-warming.htmlSummary:
"Scientists at the Max Planck Institute for Meteorology (MPI-M), Dr. Katharina Six, Dr. Silvia Kloster, Dr. Tatiana Ilyina, the late Dr. Ernst Maier-Reimer and two co-authors from the US, demonstrate that ocean acidification may amplify global warming through the biogenic production of the marine sulfur component dimethylsulphide (DMS).
It is common knowledge that fossil fuel emissions of CO2 lead to global warming. The ocean, by taking up significant amounts of CO2, lessens the effect of this anthropogenic disturbance. The "price" for storing CO2 is an ongoing decrease of seawater pH (ocean acidification1), a process that is likely to have diverse and harmful impacts on marine biota, food webs, and ecosystems. Until now, however, climate change and ocean acidification have been widely considered as uncoupled consequences of the anthropogenic CO2 perturbation2. Recently, ocean biologists measured in experiments using seawater enclosures (mesocosms)3 that DMS concentrations were markedly lower in a low-pH environment (Figure 1).
When DMS is emitted to the atmosphere it oxidizes to gas phase sulfuric acid, which can form new aerosol particles that impact cloud albedo and, hence, cool the Earth's surface. As marine DMS emissions are the largest natural source for atmospheric sulfur, changes in their strength have the potential to notably alter the Earth's radiation budget. Based on the results from the mesocosm studies the researchers from the MPI-M have established relationships between pH changes and DMS concentrations in seawater. They projected changes in DMS emissions into the atmosphere in a future climate with enhanced ocean acidification using the MPI-M Earth system model4. In the journal Nature Climate Change it is demonstrated, that modeled DMS emissions decrease by about 18 (±3)% in 2100 compared to preindustrial times as a result of the combined effects of ocean acidification and climate change. The reduced DMS emissions induce a significant positive radiative forcing of which 83% (0.4 W/m2) can, in the model, be attributed to the impact of ocean acidification alone (Figure 2).
Compared to the Earth system response to a doubling of atmospheric CO2 this is tantamount to an equilibrium temperature increase between 0.23 and 0.48 K. Simply put, their research shows that ocean acidification has the potential to speed up global warming considerably.
References:
1. Gattuso, J-P. & Hansson, L. in Ocean Acidification (eds Gattuso, J-P. & Hansson, L.) 1_20 (Oxford Univ. Press, 2011).
2. Doney, S. C., Fabry, V. J., Feely, R. A. & Kleypas, J. A. Ocean acidification: The other CO2 problem. Annu. Rev. Mar. Sci. 1,
dx.doi.org/10.1146/annurev.marine.010908.163834, 169-192 (2009).
3. Archer, S. D. et al. Contrasting responses of DMS and DMSP 102 to ocean acidification in Arctic waters. Biogeosciences 10, 103,
dx.doi.org/10.5194/bg-10-1893-2013 (2013).
4. Jungclaus, J. H. et al. Climate and carbon-cycle variability over the last millennium. Clim. Past 6, dx.doi.org/10.5194/cp-6-723-2010, 723-737 (2010)."
Furthermore, the linked 2013 article focuses on changes in the Arctic Ocean, and indicates that changes in the plankton there could also result in a positive feedback (that will likely become more important with time) associated both with lower dimethyl sulphide production and lower CO2 absorption, and again I wonder whether freshwater in the North Atlantic from possible GIS ice mass loss my kill these plankton and thus strengthen the positive feedback mechanism:
http://www.egu.eu/news/76/tiny-plankton-could-have-big-impact-on-climate/This article states:
""If the tiny plankton blooms, it consumes the nutrients that are normally also available to larger plankton species,” explains Ulf Riebesell, a professor of biological oceanography at the GEOMAR Helmholtz Centre for Ocean Research Kiel in Germany and head of the experimental team. This could mean the larger plankton run short of food.
Large plankton play an important role in carbon export to the deep ocean, but in a system dominated by the so-called pico- and nanoplankton, less carbon is transported out of surface waters. “This may cause the oceans to absorb less CO2 in the future,” says Riebesell.
The potential imbalance in the plankton food web may have an even bigger climate impact. Large plankton are also important producers of a climate-cooling gas called dimethyl sulphide, which stimulates cloud-formation over the oceans. Less dimethyl sulphide means more sunlight reaches the Earth’s surface, adding to the greenhouse effect. “These important services of the ocean may thus be significantly affected by acidification.”
Ecosystems in the Arctic are some of the most vulnerable to acidification because the cold temperatures here mean that the ocean absorbs more carbon dioxide. “Acidification is faster there than in temperate or tropical regions,” explains the coordinator of the European Project on Ocean Acidification (EPOCA), Jean-Pierre Gattuso of the Laboratory of Oceanography of Villefranche-sur-Mer of the French National Centre for Scientific Research (CNRS).
The increasing acidity is known to affect some calcifying organisms in the Arctic, including certain sea snails, mussels and other molluscs. But scientists did not know until now how ocean acidification alters both the base of the marine food web and carbon transport in the ocean. ..."
Furthermore, this article points to the free pdfs available on this topic from the following special issue of Biogenosciences
http://www.biogeosciences.net/special_issue120.html